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When formulating emulsions, selecting the right nonionic surfactant for the job can be challenging due to varying oil characteristics, demanding formulation stability requirements, and a wide variety of potential surfactants. To aid surfactant selection, hydrophilic-lipophilic balance, or HLB, is a simple descriptor of a surfactant’s relative hydrophobicity, and is one way to classify emulsifiers and solubilizers. High HLB surfactants are generally water-soluble. Low HLB surfactants are usually oil soluble. Using this system, a formulator matches the HLB of a surfactant to the HLB requirements of the application. Simple rules-of-thumb are widely recognized. For oil emulsification or solubilization in water, the composition of the oil will dictate the required surfactant HLB. For oil mixtures, approximate HLB requirements can be conveniently calculated from those of the individual oil components. Similarly, the HLB of surfactant mixtures can be readily estimated from those of the individual surfactants, a strategy known as HLB Bridging. Bridging not only enables fine tuning of HLB, but surfactant mixtures often display superior performance over single components. For your convenience, surfactant HLBs can be found in the Stepan Alkoxylate Product Guide, located within the Stepan website, as well as in product bulletins. HLB-based surfactant selection is another example of a potential challenge faced by formulators. Turn to Stepan as your partner in solving formulation challenges. Resources Stepan Alkoxylates Microsite: http://alkoxylates.stepan.com/ Full Tech Video Series: http://alkoxylates.stepan.com/alkoxyl... Alkoxylate Product Guide: http://alkoxylates.stepan.com/wp-cont... Stepan Company Website: https://www.stepan.com/default.aspx Other Tech Videos Nonionic Surfactant Phase Behavior: https://vimeo.com/237031238 Nonionic Surfactant Cloud Point: https://vimeo.com/258173268 Disclaimer: The information contained herein is based on the manufacturer’s own study and the works of others and is subject to change without prior notice. The information is not intended to be all-inclusive, including as to the manner and conditions of use, handling, storage or disposal or other factors that may involve additional legal, environmental, safety or performance considerations. Nothing contained herein grants or extends a license, express or implied, in connection with any patents issued or pending of the manufacturer or others, or shall be construed as a recommendation to infringe any patents. STEPAN COMPANY MAKES NO PRODUCT WARRANTY OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR USE, EXPRESS OR IMPLIED, AND NO OTHER WARRANTY OR GUARANTY, EXPRESS OR IMPLIED, IS MADE, INCLUDING AS TO INFORMATION REGARDING PERFORMANCE, SAFETY, SUITABILITY, STABILITY, ACCURACY, COMPLETENESS, OR ADEQUACY. Stepan Company (and its employees, subsidiaries and affiliates) shall not be liable (regardless of fault) to the vendee, its employees, or any other party for any direct, indirect, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy, furnishing, use, or reliance upon information provided herein. The vendee assumes and releases Stepan Company (and its employees, subsidiaries and affiliates) from all liability, whether in tort, contract or otherwise to the fullest extent possible under the relevant law.