The Simplifying Synthesis Ultimate Guide To Bonding In d-Metal Coordination Complexes скачать в хорошем качестве

The Simplifying Synthesis Ultimate Guide To Bonding In d-Metal Coordination Complexes

An (almost) complete inorganic chemistry guide to the bonding in d-metal coordination complexes. Section 1 describes the basic structure of inorganic metal complexes, ligand-metal interactions and isomerism, Section 2 deals with Crystal Field Theory, Ligand Field Stabilization Energy, Magnetic Properties and the Jahn-Teller Effect and Section 3 deals with Ligand Field Theory, pi-bonding, trans effect and inverted ligand fields. NMR Spectroscopy in music: J. New Music Res. 2021, 50:5, 487-501 SUPPORT THE CHANNEL ON PATREON:   / simplifyingsynthesis   Socials:   / simplifyingsynthesis     / simplifyingsyn1     / simplifyingsynthesis   References: Atkins, Overton, Rourke, Weller, Armstrong, (2010) Shriver & Atkins' inorganic chemistry. Oxford University Press. ISBN 9780199236176 J. Am. Chem. Soc. 1963, 85, 3533-3539 (Hard/Soft Concept) Dalton Trans., 2017,46, 5297-5307 (Bridged Cu complex) Dalton Trans., 2004, 1201-1207 (JT Distorted complexes) Chem. Sci., 2022,13, 737-747 (JT Distorted complexes) J. Am. Chem. Soc. 1988, 110, 7391-7398 (Thermochromic bis(diethylammonium)tetrachlorocuprate complex) Acta Cryst. 2016, 72, 40–43 (Thermochromic bis(diethylammonium)tetrachlorocuprate complex) J. Am. Chem. Soc. 1988, 110, 25, 8341–8343 (Nephelauxetic Effect) Angew. Chem., Int. Ed. Engl. 1995, 34, 80−81 (Snyder- Elusiveness of Cu"' Complexation; Preference for Trifluoromethyl Oxidation in the Formation of [Cu (I)(CF3)4] - Salts) Angew. Chem., Int. Ed. Engl. 1995, 34, 986 (Formal Oxidation State versus Partial Charge—A Comment; Reply to Snyder) J. Am. Chem. Soc. 2016, 138, 1922−1931 (Spectroscopic Evidence for a 3d10 Ground State Electronic Configuration and Ligand Field Inversion in [Cu(CF3)4] 1‑ ) Theor. Chem. Acc. 2009, 123, 67−73 (Oxidation States, Atomic Charges and Orbital Populations in Transition Metal Complexes-further studies on [Cu(CF3)4] 1‑ ) J. Am. Chem. Soc. 2016, 138, 1922—1931 (Spectroscopy of [Cu(CF3)4] 1‑ ) Angew. Chem. Int. Ed.2021,60, 26545 –2654 (Inverted Ligand Field Ag Complex) Angew. Chem. Int. Ed. 2019, 58, 13133—13139 (Inverted Ligand Field Ni Complex) Science 2019, 365, 1138−1143 (Inverted Ligand Field Cu Complex) Inorg. Chem. 2022, 61, 8, 3484–3492 (Inverted Ligand Field Au/Fe Cluster Complex) 0:00 Introduction 0:18 Coordination Chemistry 1:02 Coordination Complex Structure 1:29 Coordination Geometries 5:06 Bridging ligands 7:07 Octahedral Complexes 8:05 Optical Isomers 8:50 Coordination Structure Summary 9:18 Crystal Field Theory 10:32 Octahedral Field 12:54 Square Planar Field 17:04 Ligand Field Stabilization Energy 19:00 Jahn-Teller Effect 21:33 Thermochromism 23:31 Magnetic Properties 25:03 Ligand Field Theory 27:39 Nephelauxetic Effect 31:59 Ground State Destabilization 32:49 Kinetic Trans Effect 33:44 Inverted Ligand Fields