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Tautomerism Tautomerism is a special type of isomerism in which a single compound exists in two (or more) rapidly interconvertible structural forms (called tautomers) that differ mainly in the position of a proton (H⁺) and a double bond. These tautomers are in dynamic equilibrium with each other. Desmotropism Definition: A special case of tautomerism, where the tautomers coexist in equilibrium, but do not interconvert under normal conditions (i.e., the equilibrium is "frozen"). Key Feature: Static mixture of tautomers that do not readily convert into each other. Reason: Often due to high activation energy or steric hindrance. Common in: Some dyes and pigments, where both tautomers are stable enough to exist side-by-side but can’t interconvert easily. 🧠 Summary Table Feature Tautomerism Desmotropism Type of Isomerism Dynamic (reversible interconversion) Static (non-interconverting) Interconversion Yes, fast and reversible No (or very slow) Example Keto-enol tautomerism Some azo dyes, nitrophenols Coexistence Usually one form dominates Both forms may coexist stably Biological/Chemical Use Very common (biochem, org chem) More niche (dyes, analytical chem) ✅ Bottom Line Tautomerism = interconverting isomers (fast equilibrium). Desmotropism = non-interconverting tautomers (coexist but don't equilibrate easily). • Ring Chain Isomerism | How to identify Rin... • Parts per million (PPM) |#chemclasses • An Introduction to Spectroscopy #chemclasses, #shorts, #youtubeshorts, #shortvideos,#shortsfeed, #trending Organic Chemistry, Inorganic Chemistry, Physicsl Chmeistry, NEET, JEE, Class-12th, class 11th, CBSE, NCERT, PMT, CSIR-NET, JRF, MSc, BSc, Competetive exams, #physicswallah