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In this Perspective Video, we highlight some recent progress in the reactive scattering of "chemical probe" species such as atoms or small radicals from liquid surfaces. We emphasize in particular the evolution of this area from purely dynamical studies of the scattering mechanism. The mechanistic understanding that has now been gained is sufficiently mature to allow the same methods to be used as an effective analytical tool. The use of this approach to measure liquid surface composition and structure is illustrated through the scattering of O(3P) atoms from a common, imidazolium-based family of ionic liquids. DOI: 10.1021/jz1013032 Subscribe! http://bit.ly/AmerChemSOc Facebook! / journalofphysicalchemistry Twitter! / jphyschem For more information, please visit the Journal of Physical Chemistry Letters website: https://pubs.acs.org/journal/jpclcd You might also like: ACS Energy Letters Perspectives & Reviews: • Molecular Layer Deposition for Energy Conv... ACS Nanotation: • High-Efficiency Fog Collector: Water Unidi... Publishing Your Research 101 Series: • PYR101: George Whitesides - How to Write a... Produced by the American Chemical Society, the world’s largest scientific society. ACS is a global leader in providing access to chemistry-related information and research through its multiple databases, peer-reviewed journals and scientific conferences. Join the American Chemical Society! https://bit.ly/Join_ACS