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This is part twenty one lecture of electrochemistry. Following topics are discussed in this lecture. 1. Liquid Junction Potential 2. Example and Origin of Liquid Junction Potential 3. Definition of Liquid Junction Potential 4. Reason of Liquid Junction Potential 5. Diffusion Potential and its origin 6. Explanation of Liquid Junction Potential 7. Derivation of Liquid Junction Potential for electrolyte concentration cell reversible to cations 8. Derivation of Liquid Junction Potential for electrolyte concentration cell reversible to anions 9. Electrolyte concentration cell with transference 10. Electrolyte concentration cell without transference 11. Formula of Liquid Junction Potential 12. Dependence of Liquid Junction Potential on transport number of cations or anions. 13. Electrolyte concentration cell with transference 14. Relationship between the EMF of electrolyte concentration cell without transference and electrolyte concentration cell with transference. 15. Sign of Liquid junction potential.