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Welcome to 'Electrochemical impedance Spectroscopy' course ! This lecture covers the fundamentals of electrochemistry, focusing on the electrode-electrolyte interface and the formation of the double layer. It explains the importance of using a three-electrode system and the role of supporting electrolytes in electrochemical measurements. The three-electrode system, with a working electrode, reference electrode, and counter electrode, is necessary to accurately measure the potential of the working electrode with respect to a stable reference point. Additionally, supporting electrolytes are used to increase the conductivity of the solution and minimize potential drops across the cell, allowing for more accurate measurements. NPTEL Courses permit certifications that can be used for Course Credits in Indian Universities as per the UGC and AICTE notifications. To understand various certification options for this course, please visit https://nptel.ac.in/courses/104106105 #Electrochemistry #DoubleLayer #ThreeElectrodeSystem #SupportingElectrolyte