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From Metal to Metal-free Heterogeneous Catalysts: A Journey into more sustainable chemical processes Heterogeneous transition metal catalysts are generally based on nanoparticles, that nowadays can be synthesized with uniform size and shape. The extraordinary advances in material science support a new vision for nanoscale-inspired design and synthesis of industrially important catalysts. This precise structural and morphological control, coupled with the possibility to modulate the metal-support interactions, allowed us to have a step change increase in the activity, selectivity and stability of many industrially and environmentally important catalysts.[1-5] Furthermore, single atom catalysts[6] and metal-free[7-9] materials are becoming an essential strategy in sustainable catalysis. In this context, green organic synthesis, renewable energy conversion, pollution prevention and control are the real challenges of the 21st century and the focus of the present talk. [1] M. Cargnello, V. Doan-Nguyen, T.R. Gordon, R.E. Diaz, E. Stach, R.J. Gorte, P. Fornasiero, C.B Murray, Science 2013, 341, 771-773. [2] M. Cargnello, J.J. Delgado Jaén, J.C. Hernández Garrido, K. Bakhmutsky, T. Montini, J.J. Calvino Gámez, R.J. Gorte, P. Fornasiero, Science 2012, 337, 713. [3] G. Valenti, A. Boni, M. Melchionna, M. Cargnello, L. Nasi, G. Bertoni, R.J. Gorte, M. Marcaccio, S. Rapino, M. Bonchio, P. Fornasiero, M. Prato, F. Paolucci, Nature Communications 2016 article number: 13549. [4] N. Luo, T. Montini, J. Zhang, P. Fornasiero, E. Fonda, T. Hou, W. Nie, J. Lu, J. Liu, M. Heggen, L. Lin, C. Ma, M. Wang, F. Fan, S. Jin, F. Wang, Nature Energy 2019, 4, 575-584. [5] S.M. Hossein Hejazi, M. Shahrezaei, P. Błoński, M. Allieta, P.M. Sheverdyaeva, P. Moras, Z. Baďura, S. Kalytchuk, E. Mohammadi, R. Zbořil, Š. Kment, M. Otyepka, A. Naldoni, P. Fornasiero.; Chem Catal., 2022, 2, 1177-1190. [6] A. Bakandritsos, R.G. Kadam, P. Kumar, G. Zoppellaro, M. Medved', J. Tuček, T. Montini, O. Tomanec, P. Andrýsková, B. Drahoš, R. S. Varma, M. Otyepka, M. B. Gawande, P. Fornasiero, R. Zbořil, Adv. Mater. 2019, 31, n° 1900323 [7] D. Iglesias, A. Giuliani, M. Melchionna, S. Marchesan, A. Criado, L. Nasi, M. Bevilacqua, C. Tavagnacco, F. Vizza, M. Prato, P. Fornasiero, Chem, 2018, 4, 106 [8] G. Filippini, F. Longobardo, L. Forster, A. Criado, G. Di Carmine, C. D’Agostino, M. Melchionna, P. Fornasiero, M. Prato, Science Adv. 2020, 46, eabc9923. [9] G. Gentile, C. Rosso, A. Criado, V. Gombac, G. Filippini, M. Melchionna, P. Fornasiero, M. Prato Inorg. Chim. Acta 2022, 531, n° 120732 === About this Conference: The Confernece "Bridging the Gap: Nano meets Quantum" brings together young researchers of the Center for NanoScience (CeNS) and the Munich Center for Quantum Science and Technology (MCQST) with experienced scientists from the fields of physics and chemistry. The talks of the workshop are intended to give the graduate students and post-doctoral researchers of CeNS and MCQST an overview of current research topics on nanometer-scale and quantum science. === ▶ Conference Website: www.mcqst.de/news-and-events/events/nano-meets-quantum-2022.html ▶ CENS Website: https://www.cens.de MCQST ▶ Website: https://www.mcqst.de ▶ Twitter: / mcqst_cluster ▶ LinkedIn: / mcqst