Solvent co-intercalation in metal oxide hosts by nanoconfinement design - Simon Fleischmann скачать в хорошем качестве

Solvent co-intercalation in metal oxide hosts by nanoconfinement design - Simon Fleischmann

Electrochemical intercalation typically involves ion desolvation at the electrolyte-electrode interface, incurring kinetic limitations and strong ion-host interactions. The emerging mechanism of solvent co-intercalation, where ions intercalate together with a (partially) intact solvation shell, can mitigate these drawbacks, but has thus far been primarily explored from the viewpoint of electrolyte design. In this contribution, I will demonstrate the feasibility of regulating solvent co-intercalation by electrode nanoconfinement design. This will include examples of mono- and multivalent ions from both aqueous and non-aqueous electrolytes, underlining the universal feasibility of the approach.