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The postulates of quantum statistical mechanics are to be regarded as working hypothesis whose justification lies in the fact that they lead to results in agreement with the experiments.Such a point of view is not entirely satisfactory,because these postulates can not be independent of,and should be derivable from, the quantum mechanics of molecular system.These postulates are regarded as phenomenological statements.The postulate of random phases implies that the state of a system in equilibrium may be regarded as an incoherent superposition of eigenstates. Complete Playlist for Statistical Mechanics- • Statistical Mechanics If you want to support this channel, then you can become a member or donate here- https://www.buymeacoffee.com/advanced... This is completely voluntary, these donations can help increase the quality of the videos and the lectures overall. Stay Curious, Keep Learning! Become a member- / @advancedphysics