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In this video we are discussing the classification of materials on the basis of electrical conductivity. Based on the electrical conductivity all the materials in nature are classified as insulators, semiconductors, and conductors. An insulator is a material that offers a very low level (or negligible) of conductivity when voltage is applied. Eg: Paper, Mica, glass, quartz. Typical resistivity level of an insulator is of the order of 10^10 to 10^12 Ω-cm. A conductor is a material which supports a generous flow of charge when a voltage is applied across its terminals. i.e. it has very high conductivity. Eg: Copper, Aluminum, Silver, Gold. The resistivity of a conductor is in the order of 10^-4 and 10^-6 Ω-cm. A semiconductor is a material that has its conductivity somewhere between the insulator and conductor. The resistivity level is in the range of 10 and 104 Ω-cm. Two of the most commonly used are Silicon (Si=14 atomic no.) and germanium (Ge=32 atomic no.). Both have 4 valance electrons. The forbidden band gap is in the order of 1eV. For eg., the band gap energy for Si, Ge and GaAs is 1.21, 0.785 and 1.42 eV, respectively at absolute zero temperature (0K). At 0K and at low temperatures, the valance band electrons do not have sufficient energy to move from V to CB. Thus semiconductors act a insulators at 0K. as the temperature increases, a large number of valance electrons acquire sufficient energy to leave the VB, cross the forbidden bandgap and reach CB. These are now free electrons as they can move freely under the influence of electric field. At room temperature there are sufficient electrons in the CB and hence the semiconductor is capable of conducting some current at room temperature.