Carbon Dioxide, Part 5: Decarboxylation of Carboxylic Acids скачать в хорошем качестве

Carbon Dioxide, Part 5: Decarboxylation of Carboxylic Acids

This video is about the decarboxylation of carboxylic acids and esters for the preparation of alkanes, olefins, arenes, and organic halides. General reaction mechanisms and the thermal stability of carboxylic acids are discussed, and a number of specific examples with full experimental details are given. I've included oxidative decarboxylations leading to the formation of carbon-halogen, carbon-oxygen, or carbon-nitrogen bonds, and C-C bond forming decarboxylations. Further examples (patents are available at https://worldwide.espacenet.com/): Org. Syn. 2015, 92, 148; 2012, 89, 491; 1971, 51, 106; 73; 1970, 50, 31; 1965, 45, 25; 7; 1961, 41, 24; 1960, 40, 71; 54; 1959, 39, 46; 1957, 37, 73; 1955, 35, 32; 1953, 33, 88; 43; 1952, 32, 57; 1951, 31, 74; 25; 1950, 30, 70; 1948, 28, 38; 1947, 27, 24; 1945, 25, 33; 1944, 24, 92; 87; 1943, 23, 16; 1936, 16, 60; 1935, 15, 31; 14; 1934, 14, 58; 48; 30; 1931, 11, 20; 1929, 9, 74; 1927, 7, 60; 40; 1; 1925, 4, 77; 1922, 2, 93; J. Org. Chem. 2025, 90, 517-528; 2024, 89, 14596-14600; 7472-7477; ACS Sust. Chem. Eng. 2024, 12, 2852-2861; JACS Au 2024, 4, 2715-2745; Asian J. Org. Chem. 2024, 13, e202400308; Org. Lett. 2024, 26, 10940-10945; 4797-4802; Green Chem. 2024, 26, 2721-2729; Chem. Eur. J. 2024, 30, e202402705; Org. Proc. Res. Dev. 2024, 28, 2928-2934; Eur. J. Org. Chem. 2023, 26, e202300166; Synthesis 2023, 55, 598-608; Synlett 2023, 34, 2439-2442; Org. Lett. 2023, 25, 8970-8974; 7958-7962; 483-487; 47-52; J. Org. Chem. 2023, 88, 10252-10256; 6347-6353; 1713-1719; ACS Catal. 2023, 13, 1621-1629; 2022, 12, 4554-4559; J. Org. Chem. 2022, 87, 11871-11879; J. Am. Chem. Soc. 2022, 144, 15894-15902; 2021, 143, 5349-5354; ACS Catal. 2021, 11, 14625-14634; Chem. Rev. 2021, 121, 412-484; Ang. Chem. Int. Ed. 2021, 60, 24012-24017; Catalysts 2021, 11, 876; Chem. Comm. 2020, 56, 13868-13871; ACS Catal. 2020, 10, 9649-9661; Synlett 2020, 31, 1221-1225; 1805-1808; J. Org. Chem. 2020, 85, 5019-5026; 2019, 84, 5005-5020; 2018, 83, 12192-12206; 8233-8240; Tetrahedron Lett. 2018, 59, 4593-4596; Org. Chem. Front. 2018, 5, 2515-2521; Org. Lett. 2018, 20, 4164-4167; 3229-3232; 1413-1416; ACS Sust. Chem. Eng. 2018, 6, 7232-7238; R. Soc. Open Sci. 2018, 5, 180333; Chem. Eur. J. 2017, 23, 12900-12908; 10254; Synthesis 2017, 49, 5263-5284 (review); ACS Sust. Chem. Eng. 2017, 5, 3132-3140; Org. Lett. 2017, 19, 2318-2321; 46-49; 2016, 18, 3937-3939; 392-395; J. Org. Chem. 2016, 81, 7250-7255; 7102-7109; Adv. Syn. Catal. 2015, 357, 1229-1236; Org. Chem. Front. 2015, 2, 1352; Ang. Chem. Int. Ed. 2015, 54, 8819-8822; J. Am. Chem. Soc. 2015, 137, 11340-11348; Org. Lett. 2014, 16, 4228-4231; J. Org. Chem. 2014, 79, 10972-10980; 2013, 78, 6677-6687; J. Am. Chem. Soc. 2012, 134, 4258-4263; Synlett 2010, 2778-2779; J. Org. Chem. 2009, 74, 2620-2623; Chem. Comm. 2004, 724-725; J. Org. Chem. 2002, 67, 7861-7864; 1996, 61, 6346-6353; Tetrahedron Lett. 1986, 27, 4615-4618; Tetrahedron 1969, 25, 1197-1207.