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In this episode, we discuss the scientific and regulatory definitions of flammability and combustibility. The episode details different categories of flammable and combustible liquids based on their flashpoints and boiling points, and explains the classification systems of OSHA, GHS, and NFPA. It emphasizes the importance of understanding the flashpoint and combustibility of materials in various work environments, the implications of aerosolization, and the potential for spontaneous combustion in oily rags. The discussion covers the relevance of different test methods and standards used in hazard communication and risk assessment in industrial settings. 00:00 Introduction and Greetings 01:13 Scientific Definition of Vulnerability 01:53 OSHA GHS Flashpoint Test 04:08 NFPA Classification System 09:12 Combustible Liquids and Aerosols 13:13 Regulatory Standards and Harmonization 18:28 Practical Implications and Worker Safety 28:00 Understanding Flashpoints and Their Implications 28:44 Technical Committees and Standards 29:27 Flammability Tests and Methods 32:49 Hazard Communication and Process Safety 36:51 Challenges with Dust and Nanoparticles 43:04 Regulatory Standards and Compliance 50:32 Training and Continuous Improvement 54:14 Final Thoughts on Hazard Management