Acylation of Alcohols, Part 5: with Carbon Monoxide or Aldehydes скачать в хорошем качестве

Acylation of Alcohols, Part 5: with Carbon Monoxide or Aldehydes

This video is about alkoxycarbonylations with carbon monoxide and about oxidative acylations with aldehydes. Although acylations with carboxylic acid derivatives have been extensively optimized, these two alternative strategies may be valuable in special situations. Further examples: Carbon Monoxide: Org. Lett. 2020, 22, 2093-2098 (Cu, ArH, CHCl3); J. Org. Chem. 2020, 85, 7136-7151 (Pd, alkyne); US 10494326 (2019, Pd, MTBE); Org. Lett. 2019, 21, 6919-6923 (Co, N-alkylpyridinium salts); 4689-4693 (Cu, In, RI); ACS Catal. 2019, 9, 5545-5551 (Rh, ArH); J. Org. Chem. 2019, 84, 9907-9912 (Co, Mn, epoxide); ACS Sust. Chem. Eng. 2018, 6, 9579-9584 (Pd, ethylene); J. Am. Chem. Soc. 2018, 140, 5217-5223 (Pd, alkene, HCO2H); J. Org. Chem. 2017, 82, 4970-4976 (Pd, ArN2H3); 2016, 81, 3860-3867 (Pd, alkene); 2015, 80, 6419-6424 (Pd, alkene); 1920-1928 (Pd, ArBr); ACS Catal. 2015, 5, 4519-4529 (Pd, alkene); 2013, 3, 287-293 (Pd, ArI); J. Org. Chem. 2013, 78, 1547-1552 (Pd, RCl); Org. Lett. 2011, 13, 2495-2497 (Pd, vinyl tosylate); Org. Proc. Res. Dev. 2011, 15, 717-720 (Pd, ArI); J. Mol. Catal. A 2011, 348, 63-69 (formylation, Mo(CO)6); J. Am. Chem. Soc. 2010, 132, 3153-3158 (Pd, ArI); Org. Proc. Res. Dev. 2009, 13, 634-637 (Pd, ArI); J. Am. Chem. Soc. 2003, 125, 5523-5539 (Pd); Org. Proc. Res. Dev. 2001, 5, 572-574 (Pd, ArCl); Catal. Lett. 1996, 38, 127-131 (formylation); J. Mol. Catal. 1987, 41, 329-347 (formylation). Aldehydes: Chem. Eur. J. 2018, 24, 2370-2374 (thiazolium); Tetrahedron 2018, 74, 6584-6592 (R-O-OH); J. Org. Chem. 2017, 82, 1591-1599 (persulfate); Organometallics 2017, 36, 1461-1464 (PhCOCF3); Chem. Sci. 2016, 7, 4428-4434 (Rh); J. Am. Chem. Soc. 2015, 137, 5891-5894 (triazolium, asym); Catal. Comm. 2015, 59, 101-103 (Fe2O3, H2O2); Org. Lett. 2013, 15, 500-503 (Pd, acetone); 2012, 14, 382-385 (thiazolium); J. Am. Chem. Soc. 2010, 132, 1190-1191 (triazolium); US 20080045742 (2008, DDQ); Tetrahedron 2007, 63, 12695-12701 (Ir); Tetrahedron Lett. 2007, 48, 1033-1035 (Cu, R-O-OH); Org. Proc. Res. Dev. 1998, 2, 261-269 (Re, H2O2); Tetrahedron Lett. 1989, 30, 4001-4002 (MnO2). Carbon Dioxide: Nature Comm. 2014, 5, 3091 (Ru, alkenes). Oxidation of Alcohols to Esters: Org. Lett. 2018, 20, 4478-4481 (Co); Catal. Sci. Technol. 2014, 4, 3631-3635 (Pt, SnO2).