Catalyst-controlled Regiodivergent Oxidation of Unsymmetrical Diols with Samson Zacate скачать в хорошем качестве

Catalyst-controlled Regiodivergent Oxidation of Unsymmetrical Diols with Samson Zacate

In this Research Spotlight episode, Samson Zacate joins to share his work on catalyst-controlled regiodivergent oxidations of unsymmetrical diols. Key reference: J. Am. Chem. Soc. 2025, 147, 8118-8124. https://doi.org/10.1021/jacs.5c00330 Additional references (in order of appearance): Tojo, G.; Fernandez, M. Oxidation of Alcohols to Aldehydes and Ketones. Basis Reactions in Organic Synthesis; Springer: New York, 2006. Sigman, Miller, and Lin et al. Science 2023, 380, 706–712. Kawabata, T. Site-Selective Catalysis; Springer: Berlin, Germany, 2016. Foundational work on the preparation of new aminoxyl catalysts: Iwabuchi et al. Chem. Pharm. Bull. 2013, 61, 1197–1213. More work from our group: Lin et al. J. Am. Chem. Soc. 2024, 146, 31412–31419 and Lin et al. J. Am. Chem. Soc. 2024, 146, 31420–31432. More work with CHAMPO from our lab: Lin et al. J. Am. Chem. Soc. 2019, 141, 2825–2831.