Synthesis Workshop: Contra-Thermodynamic Positional Olefin Isomerization with Kuo Zhao (Episode 86) скачать в хорошем качестве

Synthesis Workshop: Contra-Thermodynamic Positional Olefin Isomerization with Kuo Zhao (Episode 86)

In this Research Spotlight episode, Kuo Zhao (Knowles group, Princeton) joins us to share his work on light-driven contra-thermodynamic positional olefin isomerization. Key paper: Zhao, K.; Knowles, R. R. J. Am. Chem. Soc. 2022, 144, 137−144. https://doi.org/10.1021/jacs.1c11681 Other references (in order of appearance): Roth, H. G.; Romero, N. A.; Nicewicz, D. A. Synlett, 2016, 27, 714-723. Crossley, S. W. M.; Barabé, F.; Shenvi, R. A. J. Am. Chem. Soc. 2014, 136, 16788−16791; Martinez-Erro, S.; Sanz-Marco, A.; Gómez, A. B.; Vázquez-Romero, A.; Ahlquist, M. S. G.; Martín-Matute, B. J. Am. Chem. Soc. 2016, 138, 13408−13414. For reviews, see: Synthesis, 2019, 51, 1293; Angew. Chem., Int. Ed. 2019, 58, 13654; ChemCatChem, 2014, 6, 2484; Chem. Rev., 2015, 115, 5462; Chem. Rev., 2019, 119, 2876; ChemCatChem, 2019, 11, 3343; ACS Catalysis 2020, 10, 5793. For our recent application of this concept in light-driven deracemization, see Shin, N. Y.; Ryss, J. M.; Zhang, X.; Miller, S. J.; Knowles, R. R. Science 2019, 366, 364−369. Schwarz, J. L.; Schäfers, F.; Tlahuext-Aca, A.; Lückemeier, L.; Glorius, F. J. Am. Chem. Soc. 2018, 140, 12705−12709; Mitsunuma, H.; Tanabe, S.; Fuse, H.; Ohkubo, K.; Kanai, M. Chem. Sci. 2019, 10, 3459−3465. Omoto, M.; Kato, N.; Sogon, T.; Mori, A.Tetrahedron Lett. 2001,42, 939–941. Schäfers, F.; Quach, L.; Schwarz J. L.; Saladrigas, M.; Daniliuc, C. G.; Glorius, F.; ACS Catal. 2020, 10, 11841–11847. Stamos, D. P.; Sheng, C.; Chen, S. S.; Kishi, Y. Tetrahedron Lett. 1997, 38, 6355–6358.