Synthesis Workshop: Enantioselective Synthesis of Ammonium Cations with Dr. Mark Walsh (Episode 73) скачать в хорошем качестве

Synthesis Workshop: Enantioselective Synthesis of Ammonium Cations with Dr. Mark Walsh (Episode 73)

In this Research Spotlight episode, we're joined by Dr. Mark Walsh, who takes us through his work on the enantioselective synthesis of ammonium cations (Kitching group, Durham University). The modules featured in this episode were nominated for C&EN magazine's Molecule of the Year: https://cen.acs.org/synthesis/Molecul... Key reference:  Nature 2021, 597, 70–76. ttps://doi.org/10.1038/s41586-021-03735-5 Other references (in order of appearance): Pope, W. J.; Peachey, S. J.; J. Chem. Soc. Trans. 1899, 77, 1127-1131. Havinga, E.; Biochim. Biophys. Acta. 1953, 13, 171-175. Kostyanovsky, V. R.; Mendeleev Commun., 2009, 19, 19–20. See pioneering work of: Toda, F. et al.; Angew. Chem. Int. Ed. 1993, 32, 1147-1148. Tayama, E. et al.; Tetrahedron Lett. 2007, 48, 4183-4185. Hunter, C. et al.; Chem. Sci. 2019, 10, 5943–5951. The area of non-lanthanide chiral shift NMR is expertly described here: Lacour, J. et al.; Chem. Commun. 1997, 2285-2286. Lacour, J. et al.; Org. Lett. 2002, 48, 1351-1354. Brown, J. et al.; Chem. Sci. 2013, 4, 3140-3147. The area of non-lanthanide chiral shift NMR is expertly described here: Lacour, J. et al.; Chem. Commun. 1997, 2285-2286. Lacour, J. et al.; Org. Lett. 2002, 48, 1351-1354. Brown, J. et al.; Chem. Sci. 2013, 4, 3140-3147. For studies on dynamic behaviour of ammonium salts in solution, see; Havinga, E.; Biochim. Biophys. Acta. 1953, 13, 171–175. Lehn, J. M. et al.; Chem. Asian J. 2015, 10, 2484–2496. Lee, I. et al.; J. Phys. Org. Chem. 1994, 7, 555–560.